Abstract
Combined ac- and dc-susceptibility, neutron-diffraction, and Mössbauer studies of , , and argue for the establishment of a spin-glass (SG) state below (B→0)≊130, 120, and 110 K, respectively. The SG temperature (B) decreases with application of external magnetic field B. The ac susceptibility () shows a sharp cusp at (B≊0). The isothermal and thermoremanent magnetization differ markedly and show temperature-dependent irreversibilities below (B). The Mössbauer spectra reveal onset of hyperfine splitting, indicating frozen spins below (0). The neutron-diffraction studies of and show that after switching off the external magnetic field greater than 3 T the U and Np momenta (2a site) are frozen parallel to the direction of the external field. We label the freezing temperature under high external fields , and show that it serves as the upper limit of (B) with (B→0)→. For concentrated SG systems, (0) is a reproducible value, independent of the observation time window, which indicates a true thermodynamic phase transition; the cusp in , however, is not necessarily a confirmation for the establishment of a SG state.
- Received 22 May 1990
DOI:https://doi.org/10.1103/PhysRevB.42.8507
©1990 American Physical Society