The rocksalt-structure PbS, PbSe, and PbTe semiconductors and their alloys exhibit a series of electronic-structure anomalies relative to the II-VI system, including the occurrence of direct gaps at the L point, anomalous order of band gaps and valence-band maximum energies versus anions, negative optical bowing, and negative band-gap pressure coefficients. We show that these anomalies result from the occurrence of the Pb s band below the top of the valence band, setting up coupling and level repulsion at the L point. Furthermore, we find that the topology of the frustrated octahedral structure leads to the occurrence in the random alloy of two distinct bonds for each anion-cation pair and to the predicted stabilization of bulk ordered ${\mathrm{Pb}}_2$STe CuPt-like phase.

• Received 25 February 1997

DOI:https://doi.org/10.1103/PhysRevB.55.13605