Force-velocity relation and density profiles for biased diffusion in an adsorbed monolayer

O. Bénichou, A. M. Cazabat, J. De Coninck, M. Moreau, and G. Oshanin
Phys. Rev. B 63, 235413 – Published 30 May 2001
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Abstract

We study the dynamics of a hard-core tracer particle (TP), performing a biased random walk in an adsorbed monolayer composed of mobile hard-core particles undergoing continuous exchanges with a vapor phase. In terms of an approximate approach, based on the decoupling of the third-order correlation functions, we obtain the density profiles of the monolayer particles around the TP, and derive the force-velocity relation, determining the TP terminal velocity Vtr as a function of the magnitude of the external bias and other system parameters. These results generalize, for the case of an arbitrary applied field, our earlier predictions [Phys. Rev. Lett. 84, 511 (2000)] obtained in the limit of a vanishingly small external bias. Asymptotic forms of the monolayer particle density profiles at large separations from the TP, and the behavior of Vtr in the limit of a small external bias, are found explicitly.

  • Received 31 October 2000

DOI:https://doi.org/10.1103/PhysRevB.63.235413

©2001 American Physical Society

Authors & Affiliations

O. Bénichou1,2, A. M. Cazabat3, J. De Coninck4, M. Moreau2, and G. Oshanin2

  • 1Laboratoire de Physique Théorique et Modèles Statistiques, Université Paris-Sud, 91405 Orsay Cedex, France
  • 2Laboratoire de Physique Théorique des Liquides, Université Paris 6, 4 Place Jussieu, 75252 Paris, France
  • 3Laboratoire de Physique de la Matière Condensée, Collège de France, 11 Place M.Berthelot, 75252 Paris Cedex 05, France
  • 4Centre de Recherche en Modélisation Moléculaire, Université de Mons-Hainaut, 20 Place du Parc, 7000 Mons, Belgium

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Issue

Vol. 63, Iss. 23 — 15 June 2001

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