Spectroscopic ellipsometry of graphene and an exciton-shifted van Hove peak in absorption

V. G. Kravets, A. N. Grigorenko, R. R. Nair, P. Blake, S. Anissimova, K. S. Novoselov, and A. K. Geim
Phys. Rev. B 81, 155413 – Published 6 April 2010

Abstract

We demonstrate that optical transparency of any two-dimensional system with a symmetric electronic spectrum is governed by the fine structure constant and suggest a simple formula that relates a quasiparticle spectrum to an optical absorption of such a system. These results are applied to graphene deposited on a surface of oxidized silicon for which we measure ellipsometric spectra, extract optical constants of a graphene layer and reconstruct the electronic dispersion relation near the K point using optical transmission spectra. We also present spectroscopic ellipsometry analysis of graphene placed on amorphous quartz substrates and report a pronounced peak in ultraviolet absorption at 4.6 eV because of a van Hove singularity in graphene's density of states. The peak is asymmetric and downshifted by 0.5 eV probably due to excitonic effects.

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  • Received 3 March 2010

DOI:https://doi.org/10.1103/PhysRevB.81.155413

©2010 American Physical Society

Authors & Affiliations

V. G. Kravets, A. N. Grigorenko*, R. R. Nair, P. Blake, S. Anissimova, K. S. Novoselov, and A. K. Geim

  • School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, United Kingdom

  • *Corresponding author sasha@manchester.ac.uk

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Issue

Vol. 81, Iss. 15 — 15 April 2010

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