We examine the ultrafast optical response of the crystalline and amorphous phases of the phase change material ${\mathrm{Ge}}_2{\mathrm{Sb}}_2{\mathrm{Te}}_5$ (GST) below the phase transformation threshold. Simultaneous measurement of the transmissivity and reflectivity of thin film samples yields the time-dependent evolution of the dielectric function for both phases. We then identify how lattice motion and electronic excitation manifest in the dielectric response. The dielectric response of both phases is large but markedly different. At 800 nm, the changes in amorphous GST are well described by the Drude response of the generated photocarriers, whereas the crystalline phase is better described by the depopulation of resonant bonds. We find that the generated coherent phonons have a greater influence in the amorphous phase than the crystalline phase. Furthermore, coherent phonons do not influence resonant bonding. For fluences up to 50% of the transformation threshold, the structure does not exhibit bond softening in either phase, enabling large changes of the optical properties without structural modification.

• Received 25 January 2016
• Revised 18 May 2016

DOI:https://doi.org/10.1103/PhysRevB.94.024301