Motivated by the search for gravitational waves emitted by binary black holes, we investigate the gravitational radiation field of point particles with spins within the framework of the multipolar-post-Newtonian wave generation formalism. We compute: (i) the spin-orbit (SO) coupling effects in the binary’s mass and current quadrupole moments one post-Newtonian (1PN) order beyond the dominant effect, (ii) the SO contributions in the gravitational-wave energy flux, and (iii) the secular evolution of the binary’s orbital phase up to 2.5PN order. Crucial ingredients for obtaining the 2.5PN contribution in the orbital phase are the binary’s energy and the spin-precession equations, derived in paper I of this series. These results provide more accurate gravitational-wave templates to be used in the data analysis of rapidly rotating Kerr-type black-hole binaries with the ground-based detectors LIGO, Virgo, GEO 600, and TAMA300, and the space-based detector LISA.

• Received 26 May 2006

DOI:https://doi.org/10.1103/PhysRevD.74.104034