Critical behavior of dielectric permittivity in the isotropic phase of nematogens

Aleksandra Drozd-Rzoska, Sylwester J. Rzoska, and Jerzy Zioło
Phys. Rev. E 54, 6452 – Published 1 December 1996
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Abstract

It has been shown that the temperature behavior of dielectric permittivity (ɛ) in the isotropic phase of nematogens can be described in the same way as in critical binary solutions. Hence, using a relation with the critical exponent φ=1α=0.5±0.03 it was possible to portray the results of ɛ(T) measurements in the isotropic phase of 5-heptyl-2-(4′-cyanobiphenyl)-pyrimidine and 4,4-n-octylcyanobiphenyl. The influence of the position of the permanent dipole moment on the results was tested by additional measurements in n-(p-methoxybenzylidene)-p-butylaniline. It also has been shown that a fluidlike analogy can be applied to the nonlinear dielectric effect (NDE), which describes changes of dielectric permittivity induced by a strong electric field. Measurements were conducted for the lowest frequency used in NDE studies (f=67 kHz), so the condition τf1 (with τ the relaxation time) was always fulfilled. Values of discontinuities of the isotropicnematic phase transition from both the analysis of ɛ(T) measurements and NDE studies are in good agreement.

  • Received 4 June 1996

DOI:https://doi.org/10.1103/PhysRevE.54.6452

©1996 American Physical Society

Authors & Affiliations

Aleksandra Drozd-Rzoska, Sylwester J. Rzoska, and Jerzy Zioło

  • Institute of Physics, Silesian University, ulica Uniwersytecka 4, 40-007 Katowice, Poland

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Vol. 54, Iss. 6 — December 1996

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