Computation of Elastic Scattering Phase Shifts via Analytic Continuation of Fredholm Determinants Constructed Using an L2 Basis

W. P. Reinhardt, D. W. Oxtoby, and T. N. Rescigno
Phys. Rev. Lett. 28, 401 – Published 14 February 1972
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Abstract

It is shown that the Fredholm determinant for the Lippmann-Schwinger equation may be computed for complex energies using only L2 basis functions. Analytic continuation to the real axis in the E+iε limit gives elastic scattering phase shifts over a continuous range of energies, showing that it is not necessary to explicitly enforce asymptotic boundary conditions for numerical scattering computations, and suggesting that elastic electron-atom or -ion scattering information may be obtained using standard bound-state configuration-interaction methods.

  • Received 30 December 1971

DOI:https://doi.org/10.1103/PhysRevLett.28.401

©1972 American Physical Society

Authors & Affiliations

W. P. Reinhardt, D. W. Oxtoby, and T. N. Rescigno*

  • Department of Chemistry, Harvard University, Cambridge, Massachusetts 02138

  • *National Science Foundation Predoctoral Fellow (1969-1972).

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Vol. 28, Iss. 7 — 14 February 1972

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