Abstract
Measurements of the radius of gyration and the hydrodynamic radius of colloidal silica aggregates are reported. These aggregates have fractal geometry and is proportional to for 500 Å≤≤7000 Å, with a ratio /=0.72±0.02. The results are compared with predictions for macromolecules of various shapes. The proportionality of the two radii can be understood with use of the pair correlation function of fractal objects and hydrodynamic interactions on the Oseen level. The value of the ratio remains to be explained.
- Received 5 November 1986
DOI:https://doi.org/10.1103/PhysRevLett.58.710
©1987 American Physical Society