High-Pressure Phase Diagram and Equation of State of Solid Helium from Single-Crystal X-Ray Diffraction to 23.3 GPa

H. K. Mao, R. J. Hemley, Y. Wu, A. P. Jephcoat, L. W. Finger, C. S. Zha, and W. A. Bassett
Phys. Rev. Lett. 60, 2649 – Published 20 June 1988
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Abstract

Single-crystal x-ray diffraction measurements have been performed on solid He4 from 15.6 to 23.3 GPa at 300 K with synchrotron radiation. The diffraction patterns demonstrate that the structure of the solid is hexagonal close packed over this pressure-temperature range, contrary to both the interpretation of high-pressure optical studies and to theoretical predictions. The solid is more compressible than is indicated by equations of state calculated with recently determined helium pair potentials. The results suggest that a significant revision of current views of the phase diagram and energetics of dense solid helium is in order.

  • Received 16 March 1988

DOI:https://doi.org/10.1103/PhysRevLett.60.2649

©1988 American Physical Society

Authors & Affiliations

H. K. Mao1, R. J. Hemley1, Y. Wu2, A. P. Jephcoat1, L. W. Finger1, C. S. Zha1, and W. A. Bassett3

  • 1Geophysical Laboratory, Carnegie Institution of Washington, Washington, D.C. 20008
  • 2Center for X-Ray Optics, Lawrence Berkeley Laboratory, Berkeley, California 94720
  • 3Department of Geological Sciences, Cornell University, Ithaca, New York 14853

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Vol. 60, Iss. 25 — 20 June 1988

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