Liquid-Crystalline and Helical Order in a Discotic Mesophase

Ernest Fontes, Paul A. Heiney, and Wim H. de Jeu
Phys. Rev. Lett. 61, 1202 – Published 5 September 1988
PDFExport Citation

Abstract

We have used x-ray diffraction to study oriented strands of hexa-hexylthiotriphenylene discotic liquid crystals. The low-temperature Dho phase consists of a triangular array of columns with periodic positional and incommensurate helical intracolumn order. A three-column superlattice results from the frustration imposed by molecular interdigitation in triangular symmetry. We suggest that the DhdDho transition is driven by the increase in hydrocarbon tail stiffness and length with decreasing temperature.

  • Received 4 May 1988

DOI:https://doi.org/10.1103/PhysRevLett.61.1202

©1988 American Physical Society

Authors & Affiliations

Ernest Fontes and Paul A. Heiney

  • Department of Physics and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Pennsylvania 19104

Wim H. de Jeu*

  • FOM-Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands

  • *Also at The Open University, P.O. Box 2960, 6401 DL Heerlen, The Netherlands.

References (Subscription Required)

Click to Expand
Issue

Vol. 61, Iss. 10 — 5 September 1988

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Letters

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×