Pulsed Fourier-transform NQR of <span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><mmultiscripts><mrow><mi mathvariant="normal">N</mi></mrow><mprescripts></mprescripts><mrow></mrow><mrow><mn>14</mn></mrow><mrow></mrow><mrow></mrow></mmultiscripts></mrow></math></span> with a dc SQUID

M. D. Hürlimann; C. H. Pennington; N. Q. Fan; John Clarke; A. Pines; E. L. Hahn

doi:10.1103/PhysRevLett.69.684

Pulsed Fourier-transform NQR of ${}^{14}N$ with a dc SQUID

M. D. Hürlimann, C. H. Pennington, N. Q. Fan, John Clarke, A. Pines, and E. L. Hahn

Phys. Rev. Lett. 69, 684 – Published 27 July 1992

Abstract

The zero-field free induction decay of solid ammonium perchlorate at 1.5 K has been directly detected with a dc superconducting quantum interference device. The Fourier-transform spectrum consists of three sharp lines at 17.4, 38.8, and 56.2 kHz arising from pure ${}^{14}N$ nuclear quadrupole resonance transitions. The absence of splittings and resonance transitions from dipolar-coupled proton spins is attributed to reorientation of the ammonium groups by quantum tunneling in combination with motional averaging in the three proton levels characterized by the irreducible representation T. The measured ${}^{14}N$ spin-spin relaxation time is 22±2 ms and the spin-lattice relaxation time is 63±6 ms.

Received 22 May 1992

DOI:https://doi.org/10.1103/PhysRevLett.69.684

Authors & Affiliations

M. D. Hürlimann, C. H. Pennington, N. Q. Fan, John Clarke, A. Pines, and E. L. Hahn

Department of Physics, University of California, Berkeley, Berkeley, California 94720
Department of Chemistry, University of California, Berkeley, Berkeley, California 94720
Materials Sciences Division, Lawrence Berkeley Laboratory, Berkeley, California 94720