Dynamic Light Scattering Study of Nematic and Smectic- A Liquid Crystal Ordering in Silica Aerogel

Tommaso Bellini, Noel A. Clark, and Dale W. Schaefer
Phys. Rev. Lett. 74, 2740 – Published 3 April 1995
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Abstract

The dynamical behavior of nematic and smectic- A ordering of a liquid crystal in an aerogel host is studied by quasielastic light scattering. In the nematic phase, ordered domains are comparable to the pore size and generally frozen in orientation, with remnant orientation fluctuations having paranematic dynamics for a domain size distribution appropriate to the aerogel, and the coupling between domains giving rise to an additional slow glasslike relaxation. At lower temperatures a drastic slowing down, connected with a local nematic–to–smectic- A transformation, is observed.

  • Received 25 April 1994

DOI:https://doi.org/10.1103/PhysRevLett.74.2740

©1995 American Physical Society

Authors & Affiliations

Tommaso Bellini1,2, Noel A. Clark2, and Dale W. Schaefer3

  • 1Dipartimento di Elettronic, Universita' di Pavia 27100 Pavia, Italy
  • 2Condensed Matter Laboratory, Department of Physics, University of Colorado, Boulder, Colorado 80309
  • 3Sandia National Laboratories, Albuquerque, New Mexico 87185

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Issue

Vol. 74, Iss. 14 — 3 April 1995

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