Collective Dynamics in Water by High Energy Resolution Inelastic X-Ray Scattering

F. Sette, G. Ruocco, M. Krisch, U. Bergmann, C. Masciovecchio, V. Mazzacurati, G. Signorelli, and R. Verbeni
Phys. Rev. Lett. 75, 850 – Published 31 July 1995
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Abstract

A propagating excitation with a velocity of sound of 3200±100 m/s is measured in H2O at 294 K between 4 and 14 nm1, using inelastic x-ray scattering with 5 meV energy resolution. The existence of fast sound is therefore demonstrated in an energy-momentum region much wider than that of previous neutron measurements on D2O. The equivalence of the fast sound velocity in H2O and in D2O rules out models where this mode propagates only on the hydrogen network. These results show the ability of inelastic x-ray scattering to study the collective dynamics of liquids.

  • Received 12 April 1995

DOI:https://doi.org/10.1103/PhysRevLett.75.850

©1995 American Physical Society

Authors & Affiliations

F. Sette1, G. Ruocco2, M. Krisch1, U. Bergmann1, C. Masciovecchio1,2, V. Mazzacurati2, G. Signorelli2, and R. Verbeni1

  • 1European Synchrotron Radiation Facility, B.P. 220 F-38043 Grenoble Cedex, France
  • 2Universitá di L'Aquila and Istituto Nazionale di Fisica della Materia, I-67100, L'Aquila, Italy

Comments & Replies

Sette et al. Reply:

F. Sette, G. Ruocco, M. Krisch, U. Bergmann, C. Masciovecchio, V. Mazzacurati, G. Signorelli, and R. Verbeni
Phys. Rev. Lett. 76, 3657 (1996)

Comment on “Collective Dynamics in Water by High Energy Resolution Inelastic X-Ray Scattering”

F. J. Bermejo, M. Alvarez, and S. M. Bennington
Phys. Rev. Lett. 76, 3656 (1996)

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Vol. 75, Iss. 5 — 31 July 1995

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