Anomalous Viscous Loss in Emulsions

Andrea J. Liu, Sriram Ramaswamy, T. G. Mason, Hu Gang, and D. A. Weitz
Phys. Rev. Lett. 76, 3017 – Published 15 April 1996
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Abstract

We propose a model for concentrated emulsions based on the speculation that a macroscopic shear strain does not produce an affine deformation in the randomly close-packed droplet structure. The model yields an anomalous contribution to the complex dynamic shear modulus that varies as the square root of frequency. We test this prediction using a novel light scattering technique to measure the dynamic shear modulus, and directly observe the predicted behavior over six decades of frequency and a wide range of volume fractions.

  • Received 5 September 1995

DOI:https://doi.org/10.1103/PhysRevLett.76.3017

©1996 American Physical Society

Authors & Affiliations

Andrea J. Liu1, Sriram Ramaswamy1,2, T. G. Mason3,4, Hu Gang3, and D. A. Weitz3,5

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095
  • 2Department of Physics, Indian Institute of Science, Bangalore 560 012 India
  • 3Exxon Research & Engineering Company, Annandale, New Jersey 08801
  • 4Centre de Recherche Paul Pascal, Ave. A. Schweitzer, F-33600 Pessac, France
  • 5Department of Physics and Astronomy, University of Pennsylvania, 209 S. 33rd Street, Philadelphia, Pennsylvania 19104

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Issue

Vol. 76, Iss. 16 — 15 April 1996

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