Abstract
Electronic and structural properties of the high-pressure phase of were determined by combining the methods of Mössbauer spectroscopy, x-ray diffraction, and electrical resistance, , to 80 GPa. Because of a first-order phase transition taking place in the 50–75 GPa range and accompanied by a volume decrease of , a breakdown of the electronic correlation occurred, leading to a Mott transition, a metallic and a nonmagnetic single electronic state. The high-pressure structure is of the distorted type. The accommodation of the denser phase within this six-coordinated structure is attributable to the metallic state.
- Received 1 February 1999
DOI:https://doi.org/10.1103/PhysRevLett.82.4663
©1999 American Physical Society