Chiral Symmetry Breaking in Crystallization: The Role of Convection

T. Buhse, D. Durand, D. Kondepudi, J. Laudadio, and S. Spilker
Phys. Rev. Lett. 84, 4405 – Published 8 May 2000
PDFExport Citation

Abstract

Chiral symmetry breaking in stirred crystallization of sodium chlorate ( NaClO3) occurs via the production of secondary crystals from a single “mother crystal.” Martin, Tharrington, and Wu [Phys. Rev. Lett. 77, 2826 (1996)] investigated this phenomenon and concluded that it was mechanical crushing of a crystal by the stir bar, not convection, that produces secondary crystals from a single crystal. Here we report the generation of secondary crystals of sodium chlorate when a saturated solution of sodium chlorate is simply made to flow over a sodium bromate ( NaBrO3) crystal. This clearly shows that fluid flows alone can generate and disperse secondary nuclei.

  • Received 9 September 1999

DOI:https://doi.org/10.1103/PhysRevLett.84.4405

©2000 American Physical Society

Authors & Affiliations

T. Buhse2, D. Durand1, D. Kondepudi1,*, J. Laudadio1, and S. Spilker1

  • 1Department of Chemistry, Wake Forest University, Winston-Salem, North Carolina 27109-7486
  • 2Centro de Investigaciones Quimicas, Universidad Autonoma del Estado de Morelos, Avenida Universidad 1001, Colonia Chamilpa, C.P. 62210, Cuernavaca, Morelos, Mexico

  • *Author to whom correspondence should be addressed.

References (Subscription Required)

Click to Expand
Issue

Vol. 84, Iss. 19 — 8 May 2000

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Letters

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×