Exactness of the General Two-Body Cluster Expansion in Many-Body Quantum Theory

Ernest R. Davidson
Phys. Rev. Lett. 91, 123001 – Published 16 September 2003

Abstract

We show that the exact ground-state wave function for an arbitrary two-body Hamiltonian in second-quantized, finite basis set, form cannot generally be represented by a generalized coupled-cluster operator with real finite matrix elements acting on an arbitrary initial trial function.

  • Received 30 May 2003

DOI:https://doi.org/10.1103/PhysRevLett.91.123001

©2003 American Physical Society

Authors & Affiliations

Ernest R. Davidson*

  • Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27516, USA

  • *Electronic address: erdavid@washington.edu

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Issue

Vol. 91, Iss. 12 — 19 September 2003

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