Dewetting near the Glass Transition: Transition from a Capillary Force Dominated to a Dissipation Dominated Regime

Pascal Damman, Nancy Baudelet, and Günter Reiter
Phys. Rev. Lett. 91, 216101 – Published 19 November 2003

Abstract

Dynamics and corresponding morphology of dewetting of thin polystyrene films at temperatures close to the glass transition were investigated by measuring simultaneously dewetted distance and width of the rim. Comparing the opening of cylindrical holes with the retraction of a straight contact line revealed (i) a drastic influence of the geometry (planar or radial symmetry) on the dynamics at early stages, (ii) a new logarithmic dewetting regime, and (iii) transitions between four dewetting regimes clearly indicated by changes in the shape of the rim. The complete dewetting scenario can be understood as an initial dominance of capillary driving forces, which is progressively overtaken by dissipation related to the increasing size of the rim.

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  • Received 18 July 2003

DOI:https://doi.org/10.1103/PhysRevLett.91.216101

©2003 American Physical Society

Authors & Affiliations

Pascal Damman1,*, Nancy Baudelet1, and Günter Reiter2,†

  • 1Laboratoire de Physicochimie des Polymeres, Université de Mons Hainaut, 20, Place du Parc, B-7000 Mons, Belgium
  • 2Institut de Chimie des Surfaces et Interfaces, CNRS-UHA, 15 rue Jean Starcky, BP 2488, 68057 Mulhouse CEDEX, France

  • *Electronic address: pascal.damman@umh.ac.be
  • Electronic address: G.Reiter@uha.fr

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Vol. 91, Iss. 21 — 21 November 2003

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