Phonon dispersion of Mo-stabilized γ-U measured using inelastic x-ray scattering

Z. E. Brubaker, S. Ran, A. H. Said, M. E. Manley, P. Söderlind, D. Rosas, Y. Idell, R. J. Zieve, N. P. Butch, and J. R. Jeffries
Phys. Rev. B 100, 094311 – Published 30 September 2019

Abstract

We have measured the room-temperature phonon spectrum of Mo-stabilized γU. The dispersion curves show unusual softening near the H point, q=[1/2,1/2,1/2], which may derive from the metastability of the γU phase or from strong electron-phonon coupling. Near the zone center, the dispersion curves agree well with theory, though significant differences are observed away from the zone center. The experimental phonon density of states is shifted to higher energy compared to theory and high-temperature neutron scattering. The elastic constants of γ-UMo are similar to those of body-centered cubic elemental metals.

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  • Received 11 July 2019
  • Revised 6 September 2019

DOI:https://doi.org/10.1103/PhysRevB.100.094311

©2019 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Z. E. Brubaker1, S. Ran2,3, A. H. Said4, M. E. Manley1, P. Söderlind5, D. Rosas5, Y. Idell5, R. J. Zieve6, N. P. Butch2,3, and J. R. Jeffries5

  • 1Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • 2NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
  • 3Center for Nanophysics and Advanced Materials, Department of Physics, University of Maryland, College Park, Maryland 20742, USA
  • 4Advanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, USA
  • 5Lawrence Livermore National Laboratory, Livermore, California 94550, USA
  • 6Department of Physics, University of California, Davis, California 95616, USA

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Issue

Vol. 100, Iss. 9 — 1 September 2019

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