Modeling heterogeneity and memory effects on the kinetic roughening of silica films grown by chemical vapor deposition

Fernando Ojeda, Rodolfo Cuerno, Roberto Salvarezza, Fernando Agulló-Rueda, and Luis Vázquez
Phys. Rev. B 67, 245416 – Published 27 June 2003
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Abstract

We present discrete and continuum models to describe previous experiments on growth of chemical vapor deposited silica films at 611 K and 723 K [F. Ojeda et al., Phys. Rev. Lett. 84, 3125 (2000)]. Silica films deposited at 723 K show larger surface roughness already from the early stages of growth, a fact that was not explained by a previously proposed phenomenological stochastic equation for the interface height. This larger surface roughness and the concomitant development of higher local slopes seem to be correlated with the Kardar-Parisi-Zhang asymptotic scaling observed for the high-temperature conditions. Here, we explain these features on the basis of surface heterogeneity and short-range memory effects, which are assessed for our experimental system through spectroscopic measurements. By incorporating these effects into a random deposition model and related Langevin equations with correlated noise, we are able to account for the full set of experimental observations.

  • Received 17 July 2002

DOI:https://doi.org/10.1103/PhysRevB.67.245416

©2003 American Physical Society

Authors & Affiliations

Fernando Ojeda1,*, Rodolfo Cuerno2,†, Roberto Salvarezza3,‡, Fernando Agulló-Rueda1,§, and Luis Vázquez1,∥

  • 1Instituto de Ciencia de Materiales de Madrid (CSIC), Cantoblanco, E-28049 Madrid, Spain
  • 2Departamento de Matemáticas & GISC, Universidad Carlos III de Madrid, Avenida de la Universidad 30, E-28911 Leganés, Spain
  • 3INIFTA, Sucursal 4, Casilla de Correo 16, (1900) La Plata, Argentina

  • *Present address: TECNATOM, SA, Avenida Montes de Oca 1, E-28709 San Sebastián de los Reyes, Spain. Electronic address: fojeda@tecnatom.es
  • Electronic address: cuerno@math.uc3m.es
  • Electronic address: robsalva@inifta.unlp.edu.ar
  • §Electronic address: far@icmm.csic.es
  • Electronic address: lvb@icmm.csic.es

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Issue

Vol. 67, Iss. 24 — 15 June 2003

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