Abstract
The axially symmetric center observed in crystals has been studied by the electron nuclear double resonance technique in the microwave and bands. This center is produced only in crystals grown in chlorine atmosphere and x-ray irradiated at low temperature (below ). The analysis of the spectra unambiguously confirms the structural model earlier suggested by the electron paramagnetic resonance study, as a ion strongly displaced off center along an axis, almost in the center of the square determined by the four nearest ligands. The unpaired spin densities and in the and chlorine orbitals have been determined from the resulting parameters.
- Received 3 March 2004
DOI:https://doi.org/10.1103/PhysRevB.70.024105
©2004 American Physical Society