Abstract
Spin-phonon coupling is investigated in epitaxially strained thin films with perovskite structure by means of microwave (MW) and infrared (IR) spectroscopy. In this work we focus on the composition grown on substrate. The MW complex electromagnetic response shows a decrease in the real part and a clear anomaly in the imaginary part around 150 K. Moreover, it coincides with a hardening of the lowest-frequency polar phonon seen in IR reflectance spectra. In order to further elucidate this phenomenon, low-energy muon-spin spectroscopy was carried out, signaling the emergence of antiferromagnetic order with Néel temperature () around 150 K. Thus, our results confirm that epitaxial thin films display strong spin-phonon coupling below , which may stimulate further research on tuning the magnetoelectric coupling by controlling the epitaxial strain and chemical pressure in the system.
- Received 22 August 2016
- Revised 23 December 2016
DOI:https://doi.org/10.1103/PhysRevB.95.075126
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