Diagram of the aging dynamics in laponite suspensions at low ionic strength

F. Schosseler, S. Kaloun, M. Skouri, and J. P. Munch
Phys. Rev. E 73, 021401 – Published 9 February 2006

Abstract

We measure the dynamic structure factor (DSF) of probe particles embedded in an aging laponite suspension quenched by cessation of shear and the associated relaxation time τ as a function of wave vector q and aging time tw. The different q dependences measured in the successive exponential and full aging regimes, respectively, τq2 and τq1.25, yield a weak positive q dependence for the aging time twc corresponding to the crossover between the two regimes. This implies that the full aging behavior is first seen when investigating large length scales in the aging suspension. We propose a qualitative diagram of the aging dynamics and discuss the features of the DSF of the probes and of the matrix in the two aging regimes. Consistently with the idea that the full aging regime is first observed when probing large length scales, twc is markedly shorter when the motion of the probes is tracked instead of the collective fluctuations of concentration in the matrix. The exponential aging regime is most probably related to the liquid-glass transition induced by the cessation of shear rather than to the aging of a glass.

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  • Received 3 November 2005

DOI:https://doi.org/10.1103/PhysRevE.73.021401

©2006 American Physical Society

Authors & Affiliations

F. Schosseler1, S. Kaloun2,3, M. Skouri3, and J. P. Munch2

  • 1Institut Charles Sadron, UPR 22, 6 rue Boussingault, 67083 Strasbourg Cedex, France
  • 2Institut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504, 23 rue du Loess, Boîte Postale 43, 67034 Strasbourg Cedex, France
  • 3Laboratoire d'Electronique et d'Instrumentation, Faculté des Sciences Semlalia, Université Cadi ayyad, Marrakech, Morocco

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Issue

Vol. 73, Iss. 2 — February 2006

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