Abstract
The magnetic interactions in LaCaMnCrO (, 0.50, and 0.70) are investigated by x-ray absorption spectroscopy (XAS), x-ray magnetic circular dichroism (XMCD), high-resolution x-ray powder diffraction, and bulk magnetization measurements. XAS in the Mn and Cr edges support stable single valent Cr ions and a varying Mn valence state with , while the O edge XAS spectrum reveals local maxima in the O density of states close to the Fermi level due to mixing with Mn and Cr states. A robust antiferromagnetic state is found for below K. For , combined XMCD and bulk magnetization measurements indicate a fully polarized ferrimagnetic state for the Mn and Cr spins below K. For , a reduced ferrimagnetic component dominated by Mn spins is present below K. No evidence of lattice anomalies due to cooperative charge and orbital orderings is found by x-ray diffraction for all samples. The magnetic properties of this system are rationalized in terms of a competition of ferromagnetic Mn-Mn double exchange and antiferromagnetic Cr-Cr and Cr-Mn superexchange interactions.
2 More- Received 6 May 2011
DOI:https://doi.org/10.1103/PhysRevB.85.104401
©2012 American Physical Society