The effect of nanolubrication on wear and friction resistance between sliding surfaces

Studies on this topic have shown the remarkable lubricating properties, viz. friction-reducing and anti-wear, of certain nanoparticles. This makes them potential candidates for replacing the lubrication additives currently used in automobile lubricants, especially because the latter is known to be pollutants and less efficient in some specific conditions. This has not gone unnoticed to professionals in the sector, including those commercializing these additives, the oil companies and the car industry, all of whom are following this burgeoning research area with keen interest. All of them are faced with the problem of providing lubricants that meet the needs of the technological evolution of engines while respecting ever-stricter environmental norms.

The impact of copper oxide (CuO) and zinc oxide (ZnO) nanoparticles on the tribological properties of the SAE-40 pure diesel oil is studied in this paper. The two nanoparticles are not oxide or deteriorate with the base oil. The average size of CuO and ZnO nanoparticles is 40 and 20 nm, respectively. Nanoparticle concentrations of 0.1 Wt.%, 0.2 Wt.%, 0.3 Wt.%, 0.4 Wt.% and 0.5 Wt.% are tested using a pin-on-disk tribometer to evaluate their impact on friction and wear. The test is carried out at different loads and rotating speeds of 58.86 N and 300 rpm, 39.24 N and 500 rpm and 78.48 N and 900 rpm at room temperature, respectively.

The obtained results of the nanolubricants are compared with those of pure diesel oil in terms of % improvement in tribological properties. However, it is observed that an increase in the nanoparticle concentrations does not guarantee to enhance the tribological properties. Similarly, increasing the applied load and the rotating speed does not lead to improving the anti-friction and anti-wear properties. The results obtained revealed that the optimal improvements in the anti-friction and anti-wear properties of the pure oil are 69% and 77% when CuO nanoparticle concentrations of 0.3 Wt.% and the ZnO nanoparticle concentrations of 0.1 Wt.% are used, where the applied load and rotating speed are 39.24 N and 500 rpm, respectively. It has also been noticed that the CuO nanolubricants have a significant impact on the anti-friction property compared with ZnO nanolubricants.

All these nanoparticles have been the subject of detailed investigation in this research and many key issues have been tackled, such as the conditions leading to these properties, the lubrication mechanisms coming into play, the influence of parameters such as size, structure and morphology of the nanoparticles on their tribological properties/lubrication mechanisms and the interactions between the particles and the lubricant co-additives. To answer such questions, state-of-the-art characterization techniques are required, often in situ, and sometimes an extremely complex set up. Some of these can even visualize the behavior of a nanoparticle in real time during a tribological test. The research on this topic has given a good understanding of the way these nanoparticles behave, and we can now identify the key parameters to be adjusted when optimizing their lubrication properties.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-08-2022-0234/