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Investigation of lead thiosulfate photolysis in aqueous solutions

  • Photochemistry
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Abstract

A model of photolysis of PbS2O3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS2O3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition of the system a whole to the activated state, which is decomposed by the solvent. The interaction of the primary photolysis products with PbS2O3 results in the formation of final products.

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Authors and Affiliations

  1. Tomsk Polytechnic University, pr. Lenina 30, Tomsk, 634050, Russia

    N. B. Egorov

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  1. N. B. Egorov
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Correspondence to N. B. Egorov.

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Original Russian Text © N.B. Egorov, 2014, published in Khimiya Vysokikh Energii, 2014, Vol. 48, No. 1, pp. 57–62.

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Egorov, N.B. Investigation of lead thiosulfate photolysis in aqueous solutions. High Energy Chem 48, 37–41 (2014). https://doi.org/10.1134/S0018143914010056

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  • DOI: https://doi.org/10.1134/S0018143914010056

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