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Preparation of nanocrystalline VMg(OH) x and VO x · MgO from organometallic precursors

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Abstract

A process is proposed for the synthesis of nanocrystalline VMg(OH) x and VO x · MgO with specific surface areas of up to 1200 and 470 m2/g, respectively. The synthesized VO x · MgO oxides consist of nanocrystals (2′–5 nm), which form platelike agglomerates. As distinct from conventional impregnation of magnesium oxide, the aerogel process for VO x · MgO synthesis ensures a uniform vanadium distribution in MgO.

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References

  1. Mishakov, I.V., Zaikovskii, V.I., and Heroux, D.S., CF2Cl2 Decomposition over Nanocrystalline MgO: Evidence for Long Induction Periods, J. Phys. Chem. B, 2005, no. 109, pp. 6982–6989.

  2. Volodin, A.M., Bedilo, A.F., Heroux, D.S., et al., Nanoscale Oxides As Destructive Sorbents for Halogenated Hydrocarbons, Surf. Chem. Biomed. Environ. Sci., 2006, no. 3, pp. 403–412.

  3. Balderas-Tapia, L., Hernandez-Perez, I., Schacht, P., et al., Influence of Reducibility of Vanadium-Magnesium Mixed Oxides on the Oxidative Dehydrogenation of Propane, Catal. Today, 2005, nos. 107–108, pp. 371–376.

  4. Pak, C., Bell, A.T., and Tilley, T.D., Oxidative Dehydrogenation of Propane over Vanadia-Magnesia Catalysts Prepared by Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO, J. Catal., 2002, no. 206, pp. 49–59.

  5. Drits, V.A. and Sakharov, B.A., Rentgenostrukturnyi analiz smeshannosloinykh mineralov (X-Ray Structure Analysis of Mixed-Layer Minerals), Moscow: Nauka, 1976.

    Google Scholar 

  6. Utamapanya, S., Klabunde, K.J., and Schlup, J.R., Nanoscale Metal Oxide Particles/Clusters As Chemical Reagents. Synthesis and Properties of Ultrahigh Surface Area Magnesium Hydroxide and Magnesium Oxide, Chem. Mater., 1991, no. 3, pp. 175–181.

  7. Labajos, F.M., SaAnchez-Montero, M.J., Holgado, M.J., and Rives, V., Thermal Evolution of V(III)-Containing Layered Double Hydroxides, Thermochim. Acta, 2001, no. 370, pp. 99–104.

  8. Fedorov, P.P., Tkachenko, E.A., Kuznetsov, S.V., et al., Preparation of MgO Nanoparticles, Neorg. Mater., 2007, vol. 43, no. 5, pp. 574–576 [Inorg. Mater. (Engl. Transl.), vol. 43, no. 5, pp. 502–504].

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    E. V. Ilyina, I. V. Mishakov & A. A. Vedyagin

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  1. E. V. Ilyina
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  2. I. V. Mishakov
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  3. A. A. Vedyagin
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Correspondence to E. V. Ilyina.

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Original Russian Text © E.V. Ilyina, I.V. Mishakov, A.A. Vedyagin, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 11, pp. 1353–1357.

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Ilyina, E.V., Mishakov, I.V. & Vedyagin, A.A. Preparation of nanocrystalline VMg(OH) x and VO x · MgO from organometallic precursors. Inorg Mater 45, 1267–1270 (2009). https://doi.org/10.1134/S0020168509110144

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  • DOI: https://doi.org/10.1134/S0020168509110144

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