Abstract
The electrical properties of layered perovskite-like compounds with the general formula Bim + 1Fem − 3Ti3O3m + 3 have been studied in relation to their physicochemical properties and structure.
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Aurivillius, B., Mixed Bismuth Oxides with Layer Lattices. I, Ark. Kemi, 1949, vol. 1, no. 1, pp. 463–471.
Smolenskii, G.A., Isupov, V.A., and Agranovskaya, A.I., A New Group of Ferroelectrics (with Layered Structure): I, Fiz. Tverd. Tela (Leningrad), 1959, vol. 1, no. 1, pp. 169–170.
Morozov, M.I. and Gusarov, V.V., Synthesis of Am − 1 Bi2MmO3m + 3 Compounds in the Bi4Ti3O12-BiFeO3 System, Neorg. Mater., 2002, vol. 38, no. 7, pp. 867–874 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 7, pp. 723–729].
Lomanova, N.A., Morozov, M.I., Ugolkov, V.L., and Gusarov, V.V., Properties of Aurivillius phases in the Bi4Ti3O12-BiFeO3 System, Neorg. Mater., 2006, vol. 42, no. 2, pp. 225–231 [Inorg. Mater. (Engl. Transl.), vol. 42, no. 2, pp. 189–195].
Lomanova, N.A. and Gusarov, V.V., Effect of the Phase Composition of Starting Materials on the Formation of the Layered Perovskite-Like Compound Bi7Fe3Ti3O21, Zh. Neorg. Khim., 2010, vol. 55, no. 10, pp. 1634–1638.
Rao, C.N.R. and Raveau, B., Transition Metal Oxides: Structure, Properties and Synthesis of Ceramic Oxides, New York: Wiley-VCH, 1998, pp. 74–75.
Isupov, V.A., Some Distinctive Features of Am − 1Bi2MmO3m + 3 Layered Ferroelectrics, Fiz. Tverd. Tela (S.-Peterburg), 1997, vol. 39, no. 1, pp. 135–136.
Kalinkin, A.N. and Skorikov, V.M., Toroidal Spin Ordering in BiFeO3, GaFeO3, and Cr2O3 in the Faddeev Model with a Magnetic Field, Neorg. Mater., 2009, vol. 45, no. 2, pp. 227–230 [Inorg. Mater. (Engl. Transl.), vol. 45, no. 2, pp. 189–192].
Isupov, V.A., Curie Temperatures of Am − 1Bi2MmO3 m + 3 Layered Ferroelectrics, Neorg. Mater., 1997, vol. 33, no. 9, pp. 1106–1110 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 9, pp. 936–940].
Srinivas, K., Sarah, P., and Suryanarayana, S.V., Impedance Spectroscopy Study of Polycrystalline Bi6Fe2Ti3O18, Bull. Mater. Sci., 2003, vol. 26, no. 2, pp. 247–253.
Srinivas, A., Mahesh Kumar, M., Suryanarayana, S.V., and Bhimasankaram, T., Investigation of Dielectric and Magnetic Nature of Bi7Fe3Ti3O21, Mater. Res. Bull., 1999, vol. 34, no. 6, pp. 989–996.
Amirov, A.A., Batdalov, A.B., Kallaev, S.N., et al., Thermal, Magnetic, and Dielectric Properties of the BiFeO3 and Bi0.95La0.05FeO3 Multiferroics, Fiz. Tverd. Tela (S.-Peterburg), 2009, vol. 51, no. 6, pp. 1123–1126.
Patri, S.K., Choudhary, R.N.P., and Samantaray, B.K., Dielectric and Electrical Properties of Bi9Fe5Ti4O29 Nanoceramics, J. Alloys Compd., 2008, vol. 459, pp. 333–337.
Jonscher, A.K., Dielectric Relaxation in Solids, J. Phys. D: Appl. Phys, 1999, vol. 32, pp. 57–70.
Jianding, Y., Naokiyo, K., Yasutomo, A., et al., Containerless Solidification of Oxide Material Using an Electrostatic Levitation Furnace in Microgravity, J. Cryst. Growth, 2001, vol. 231, pp. 568–576.
Morozov, M.I., Lomanova, N.A., and Gusarov, V.V., A Detailed Study of BiFeO3 Formation in Mixtures of Bi2O3 and Fe2O3, Zh. Obshch. Khim., 2003, vol. 73, no. 11, pp. 1772–1776.
Kartavtseva, M.S., Gorbenko, O.Yu., Kaul’, A.R., and Savinov, S.A., BiFeO3 Multiferroic Thin Films Grown by Metalorganic Chemical Vapor Deposition, Poverkhnost, 2008, vol. 1, pp. 3–14.
Uchino, K. and Nomura, S., Critical Exponents of the Dielectric Constant in Diffused-Phase-Transition Crystals, Ferroelectr., Lett. Sect., 1982, vol. 44, pp. 55–61.
Jartych, E., Mazurek, M., Lisinska-Czekaj, A., and Czekaj, D., Hyperfine Interactions in Some Aurivillius Bim + 1Fem − 3Ti3O3m + 3 Compounds, J. Magn. Magn. Mater., 2010, no. 322, pp. 51–55.
Lomanova, N.A. and Gusarov, V.V., Phase Relations in the BiFeO3-Bi4Ti3O12 Join of the Bi2O3-TiO2-Fe2O3 System, Zh. Neorg. Khim., 2010 (in press).
Cole, K.S. and Cole, R.H., Dispersion and Absorption in Dielectrics, J. Chem. Phys., 1941, vol. 9, pp. 341–351.
Subbanna, G.N., Guru, Row T.N., and Rao, C.N.R., Structure and Dielectric Properties of Recurrent Intergrowth Structures Formed by the Aurivillius Family of Bismuth Oxides of the Formula Bi2An − 1BnO3n + 3, J. Solid State Chem., 1990, vol. 86, no. 2, pp. 206–211.
Kharitonova, E.P. and Voronkova, V.I., Phase Transitions and Electrical Properties of Bim + 1Fem − 3Ti3O3m + 3 Aurivillius Phases, Fazovye Perekhody, Uporyadoch. Sostoyaniya Nov. Mater., 2008.01.09. http://www.ptosnm.ru/catalog/i/334.
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Original Russian Text © N.A. Lomanova, V.V. Gusarov, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 4, pp. 477–482.
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Lomanova, N.A., Gusarov, V.V. Electrical properties of perovskite-like compounds in the Bi2O3-Fe2O3-TiO2 system. Inorg Mater 47, 420–425 (2011). https://doi.org/10.1134/S0020168511040169
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DOI: https://doi.org/10.1134/S0020168511040169