Skip to main content
SpringerLink
Log in

Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

By the interaction between (Et4N)2[Mo2O2S8] and I2 in DMF with a subsequent addition of 2,2′-bipyridine or 1,10-phenanthroline, new binuclear complexes [Mo2O2S2I2(bipy)2] (1) and [Mo2O2S2I2(phen)2] (2) are obtained. The structure of [Mo2O2S2I2(bipy)2] is determined using single crystal X-ray diffraction. The compounds are characterized by elemental analysis and IR spectra. The [MoO(S2)2(bipy)] complex as a product of oxidative destruction of 1 is isolated and characterized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. E. Fedorov, Yu. V. Mironov, N. G. Naumov, M. N. Sokolov, and V. P. Fedin, Usp. Khim., 76, No. 6, 571–595 (2007).

    Article  Google Scholar 

  2. R. Llusar and C. Vicent, Coord. Chem. Rev., 254, No. 14, 1534 (2011).

    Google Scholar 

  3. M. N. Sokolov, A. L. Gushchin, D. Y. Naumov et al., Inorg. Chem., 44, No. 7, 2431 (2005).

    Article  CAS  Google Scholar 

  4. A. V. Virovets, A. L. Gushchin et al., J. Struct. Chem., 47, No. 2, 326 (2006).

    Article  CAS  Google Scholar 

  5. A. L. Gushchin, K. A. Kovalenko, M. N. Sokolov et al., Russ. Chem. Bull., 56, 1707 (2007).

    Article  CAS  Google Scholar 

  6. M. N. Sokolov, P. A. Abramov, A. L. Gushchin, I. V. Kalinina, D. Y. Naumov, A. V. Virovets, E. V. Peresypkina, C. Vicent, R. Llusar, and V. P. Fedin, Inorg. Chem., 44, No. 22, 8116 (2005).

    Article  CAS  Google Scholar 

  7. A. L. Gushchin, M. N. Sokolov, D. Yu. Naumov, and V. P. Fedin, Russ. Chem. Bull., 55, 1966 (2006).

    Article  CAS  Google Scholar 

  8. A. L. Gushchin, R. Llusar, D. Recatala, and P. A. Abramov, Russ. J. Coord. Chem., 38, No. 3, 173 (2012).

    Article  CAS  Google Scholar 

  9. A. L. Gushchin, M. N. Sokolov, E. V. Peresypkina et al., Eur. J. Inorg. Chem., 25, 3964 (2008).

    Article  Google Scholar 

  10. A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, and H. Pettersson, Chem. Rev., 110, No. 11, 6595 (2010).

    Article  CAS  Google Scholar 

  11. D. Coucouvanis, A. Toupadakis, and A. Hadjikyriacou, Inorg. Chem., 27, No. 19, 3272 (1988).

    Article  CAS  Google Scholar 

  12. K. Prasanta Chakrabarty, Samaresh Bhattacharya, Cortlandt G. Pierpont, and Ramgopal Bhattacharyya, Inorg. Chem., 31, No. 17, 3573 (1992).

    Article  CAS  Google Scholar 

  13. G. M. Sheldrick, SADABS, Program for Empirical X-ray Absorption Correction, Bruker AXS (1990–2007).

    Google Scholar 

  14. G. M. Sheldrick, SHELXTL, Programs for Structure Solution and Refinement, Bruker AXS (1990–2007).

    Google Scholar 

  15. Kazuo Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds: Applications in Coordination Organometallic, and Bioinorganic Chemistry, John Wiley & Sons, Hoboken, NJ (2009).

    Google Scholar 

  16. J. S. Strukl and J. L. Walter, Spectrochim. Acta. Part A, 27, No. 2, 209 (1971).

    Article  CAS  Google Scholar 

  17. J. S. Strukl and J. L. Walter, Spectrochim. Acta, Part A: Mol. Biomol. Spectr., 27, No. 2, 223 (1971).

    Article  CAS  Google Scholar 

  18. K. Krishnan and R. A. Plane, Spectrochim. Acta, Part A: Mol. Biomol. Spectr., 25, No. 4, 831 (1969).

    Article  CAS  Google Scholar 

  19. Z. Qingwei, K. Starke, C. Schulzke, A. Hofmeister, and J. Magull, Inorg. Chim. Acta, 360, No. 10, 3400 (2007).

    Article  Google Scholar 

  20. R. Aguado, J. Escribano, M. Pedrosa, A. De Cian, R. Sanz, and F. Arnáiz, Polyhedron, 26, No. 14, 3842 (2007).

    Article  CAS  Google Scholar 

  21. J. Mizatani, H. Imoto, and T. Saito, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 53, 47 (1997).

    Article  Google Scholar 

  22. J. E. Drake, A. G. Mislanka, and R. Ratnani Inorg. Chem., 35, No. 9, 2665 (1996).

    Article  CAS  Google Scholar 

  23. F. H. Allen Acta Crystallogr., B58, 380 (2002).

    CAS  Google Scholar 

  24. H. Arzoumanian, R. Bakhtchadjian, R. Atencio, A. Briceno, G. Verde, and G. Agrifoglio, J. Mol. Cat. A: Chem., 260, No. 2, 197 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. L. Gushchin, Yu. L. Laricheva, N. I. Alferova, A. V. Virovets & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    A. L. Gushchin & M. N. Sokolov

Authors
  1. A. L. Gushchin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. L. Laricheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. I. Alferova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Virovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. N. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. L. Gushchin.

Additional information

Original Russian Text Copyright © 2013 by A. L. Gushchin, Yu. L. Laricheva, N. I. Alferova, A. V. Virovets, M. N. Sokolov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 54, No. 4, pp. 707–713, July–August, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gushchin, A.L., Laricheva, Y.L., Alferova, N.I. et al. Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure. J Struct Chem 54, 752–758 (2013). https://doi.org/10.1134/S0022476613040148

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476613040148

Keywords

Search

Navigation