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Synthesis and Molecular Structure of the Zinc(II) Complex Bearing an N, S Donor Ligand

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Abstract

The reaction between zinc(II) acetate dihydrate and ((1H-indol-3-yl)methylene)-N-methylhydrazinecarbothioamide (L) in methanol results in the formation of Zn(II) complex [Zn(C11H11N4S)2] (1). The complex is characterized by CHNS and various spectroscopic analyses. The structure of the complex is determined by the single crystal X-ray diffraction technique. XRD reveals that the Zn(II) complex crystallizes in the triclinic system with the P-1 space group and has a distorted tetrahedral geometry. Two ligand molecules are coordinated to the Zn(II) ion in the bidentate monobasic (NS−) fashion.

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Authors and Affiliations

  1. Department of Chemistry, National Institute of Technology, Tiruchirappalli, India

    J. Haribabu & R. Karvembu

  2. Department of Chemistry, Saranathan College of Engineering, Tiruchirappalli, India

    S. Priyarega

  3. Department of Chemistry, Texas A & M University, College Station, Texas, USA

    N. S. P. Bhuvanesh

Authors
  1. J. Haribabu
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  2. S. Priyarega
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  3. N. S. P. Bhuvanesh
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  4. R. Karvembu
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Corresponding author

Correspondence to R. Karvembu.

Additional information

Additional Information

CCDC 1907485 contains the supplementary crystallographic data for 1. These data can be downloaded free of charge form the Cambridge Crystallographic Data Center viawww.ccdc.cam.ac.uk/datarequest.cif or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033 or e-mail: deposit@ccdc.cam.ac.uk.

Conflict of Interests

The authors declare that they have no conflict of interests.

Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 1, pp. 71–77.

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Haribabu, J., Priyarega, S., Bhuvanesh, N.S.P. et al. Synthesis and Molecular Structure of the Zinc(II) Complex Bearing an N, S Donor Ligand. J Struct Chem 61, 66–72 (2020). https://doi.org/10.1134/S0022476620010072

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  • DOI: https://doi.org/10.1134/S0022476620010072

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