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Factors determining the chemoselectivity of phosphorus-modified palladium catalysts in the hydrogenation of chloronitrobenzenes

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Abstract

The precursor nature effect on the state of the Pd–P surface layer in palladium catalysts and on their properties in the liquid-phase hydrogenation of chloronitrobenzenes under mild conditions has been investigated. A general feature of the Pd–P-containing nanoparticles obtained from different precursors and white phosphorus at P/Pd = 0.3 (PdCl2 precursor) and 0.7 (Pd(acac)2 precursor) is that their surface contains palladium in phosphide form (BE(Pd3d 5/2) = 336.2 eV and BE(Р2р) = 128.9 eV) and Pd(0) clusters (BE(Pd3d5/2) = 335.7 eV). Factors having an effect on the chemoselectivity of the palladium catalysts in chloronitrobenzenes hydrogenation are considered, including the formation of small palladium clusters responsible for hydrogenation under mild conditions.

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Authors and Affiliations

  1. Irkutsk State University, Irkutsk, 664003, Russia

    N. I. Skripov, L. B. Belykh, T. P. Sterenchuk & F. K. Schmidt

  2. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033, Russia

    V. V. Akimov & V. L. Tauson

Authors
  1. N. I. Skripov
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  2. L. B. Belykh
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  3. T. P. Sterenchuk
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  4. V. V. Akimov
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  5. V. L. Tauson
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  6. F. K. Schmidt
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Correspondence to L. B. Belykh.

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Original Russian Text © N.I. Skripov, L.B. Belykh, T.P. Sterenchuk, V.V. Akimov, V.L. Tauson, F.K. Schmidt, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 1, pp. 36–48.

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Skripov, N.I., Belykh, L.B., Sterenchuk, T.P. et al. Factors determining the chemoselectivity of phosphorus-modified palladium catalysts in the hydrogenation of chloronitrobenzenes. Kinet Catal 58, 34–45 (2017). https://doi.org/10.1134/S0023158417010104

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  • DOI: https://doi.org/10.1134/S0023158417010104

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