Skip to main content
SpringerLink
Log in

Interaction of micas with nickel sulfate solutions

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The interaction of natural biotites with dilute nickel sulfate solutions at various pHs are studied by X-ray powder diffraction, thermogravimetric analysis, and chemical analysis. K ⇆ Ni, Mg ⇆ Ni, and to a lesser extent Fe ⇆ Ni ion exchange is shown to occur. Nickel can both enter octahedral layers and act as an interlayer cation. Tetrahedral layers have a virtually invariable composition. The mechanoactivation of biotites enhances exchange reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. M. Klyarovskii, G. M. Gusev, D. K. Arkhipenko, et al., in Quantitative Mineal and Rock Analyses by Physical Methods (SO AN SSSR, Novosibirsk, 1965), No. 32, p. 63 [in Russian].

    Google Scholar 

  2. The X-ray Identification and Crystal Structures of Clay Minerals, Ed. by G. Brown (London, 1961; Mir, Moscow, 1965).

  3. V. I. Mikheev, X-ray Identification of Minerals (Gosgeoltekhizdat, Moscow, 1957) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resourses, Kola Research Center, Russian Academy of Sciences, ul. Fersmana 26, Apatity, 198209, Russia

    V. N. Makarov, I. P. Kremenetskaya, D. V. Makarov, O. P. Korytnaya & T. N. Vasil’eva

Authors
  1. V. N. Makarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Kremenetskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. V. Makarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. P. Korytnaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. N. Vasil’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. V. Makarov.

Additional information

Original Russian Text © V.N. Makarov, I.P. Kremenetskaya, D.V. Makarov, O.P. Korytnaya, T.N. Vasil’eva, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 1, pp. 16–27.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makarov, V.N., Kremenetskaya, I.P., Makarov, D.V. et al. Interaction of micas with nickel sulfate solutions. Russ. J. Inorg. Chem. 53, 11–21 (2008). https://doi.org/10.1134/S0036023608010038

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023608010038

Keywords

Search

Navigation