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Structural organization of the tetranuclear zinc di-iso-propyl phosphorodithioate complex [Zn4O{S2P(O-iso-C3H7))2}6] as probed by single-crystal x-ray diffraction and 13C and 31P CP/MAS NMR

  • Physical Methods of Investigation
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Abstract

The zinc O,O’-di-iso-propyl phosphorodithioate complex [Zn4O⨑ub;S2P(O-iso-C3H7)2⫂ub;6] (I) has been synthesized and characterized by multinuclear MAS NMR (13C, 31P). The metal core of the tetranuclear structure of I, determined by single-crystal X-ray diffraction, is a tetrahedron centered by an oxygen atom. All Dtph ligands are structurally nonequivalent and act as μ2 bridges combining pairs of zinc atoms. Bonding of all metal atoms to the μ4 oxygen atom provides additional stabilization of the structure. For 31P NMR signals, the chemical shift anisotropy δaniso and the asymmetry parameter η were calculated, which allowed to assign them to the phosphorus positions in the structure of I.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Division, Russian Academy of Sciences, Relochnyi per. 1, Blagoveshchensk, 675000, Russia

    A. V. Ivanov

  2. Amur State University, Ignat’evskoe sh. 21, Blagoveshchensk, 675027, Russia

    T. A. Rodina & S. I. Lavrent’eva

  3. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. V. Gerasimenko

  4. Luleå University of Technology, S-971 87, Luleå, Sweden

    O. N. Antzutkin

Authors
  1. T. A. Rodina
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  2. A. V. Ivanov
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  3. S. I. Lavrent’eva
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  4. A. V. Gerasimenko
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  5. O. N. Antzutkin
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Original Russian Text © T.A. Rodina, A.V. Ivanov, S.I. Lavrent’eva, A.V. Gerasimenko, O.N. Antzutkin, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 7, pp. 1182–1193.

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Rodina, T.A., Ivanov, A.V., Lavrent’eva, S.I. et al. Structural organization of the tetranuclear zinc di-iso-propyl phosphorodithioate complex [Zn4O{S2P(O-iso-C3H7))2}6] as probed by single-crystal x-ray diffraction and 13C and 31P CP/MAS NMR. Russ. J. Inorg. Chem. 53, 1098–1109 (2008). https://doi.org/10.1134/S003602360807019X

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  • DOI: https://doi.org/10.1134/S003602360807019X

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