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Synthesis and structure of quasi-one-dimensional zinc oxide doped with manganese

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Abstract

Nanotubes of manganese-doped zinc oxide Zn1 − x Mn x O (0 ≤ x ≤ 0.2) were synthesized by heating the Zn1 − x Mn x (HCOO)(OCH2CH2O)1/2 precursor in air at 500°C. The precursor with extended crystals was synthesized by a solvothermal method based on heat treatment of a mixture of Zn1 − x Mn x (HCOO)2 · 2H2O with an ethylene glycol excess at 100–130°C. The tubular morphology of Zn1 − x Mn x O particles was identified by transmission electron microscopy. Tubular quasi-one-dimensional particles were shown to have a nanodispersed polycrystalline structure, the size of separate crystallites being from 5 to 20 nm. X-ray photoelectron spectroscopy suggested that the manganese distribution on the outer surface layer of Zn1 − x Mn x O nanotubes is nonuniform.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    O. I. Gyrdasova, V. N. Krasil’nikov, E. V. Shalaeva, M. V. Kuznetsov & A. P. Tyutyunnik

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  1. O. I. Gyrdasova
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  2. V. N. Krasil’nikov
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  3. E. V. Shalaeva
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  4. M. V. Kuznetsov
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  5. A. P. Tyutyunnik
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Original Russian Text © O.I. Gyrdasova, V.N. Krasil’nikov, E.V. Shalaeva, M.V. Kuznetsov, A.P. Tyutyunnik, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 1, pp. 78–85.

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Gyrdasova, O.I., Krasil’nikov, V.N., Shalaeva, E.V. et al. Synthesis and structure of quasi-one-dimensional zinc oxide doped with manganese. Russ. J. Inorg. Chem. 57, 72–78 (2012). https://doi.org/10.1134/S0036023612010111

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  • DOI: https://doi.org/10.1134/S0036023612010111

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