Abstract
A phase transition in Ca12Al14O33 has been discovered and investigated by thermogravimetric analysis, differential scanning calorimetry, dilatometry, and high-temperature X-ray diffraction. The phase transition occurs at 922 ± 45 K (ΔH = −406 ± 13 kJ/mol, ΔS = −440 ± 14 J/(mol K)) and is presumably a first-order one. It does not change the symmetry of the cationic subsystem. The phase transition is difficult to reveal because the material changes its mass, probably by releasing water bound in several different ways.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
G. Hentschel, Neues Jahrb. Mineral. Monatsh., No. 1, 22 (1964).
K. Kajihara, S. Matsuishi, K. Hayashi, et al., J. Phys. Chem. 111, 14855 (2007).
M. Ruszac, S. Witkowski, and Z. Sojka, Res. Chem. Intermed. 33, 689 (2007).
H. Hosono and Y. Abe, Inorg. Chem. 26, 1192 (1987).
M. Lacedra, J. Irvine, F. P. Glasser, and A. R. West, Nature 332, 525 (1988).
K. Hayashi, M. Hirano, S. Matsuishi, and H. Hosono, J. Am. Chem. Soc. 124(5), 738 (2002).
J. H. Welch, Chemistry of Cements (Academic Press, London, 1964), Vol. 1.
R. W. Nurse, J. H. Welch, and A. J. Majumdar, Trans. Br. Ceram. Soc. 64, 323 (1965).
W. Büssem and A. Eitel, Z. Kristallogr. 95, 175 (1936).
A. K. Chatterjee and G. I. Zhmoidin, J. Mater. Sci. 9, 1073 (1974).
B. Hallstedt, J. Am. Ceram. Soc. 73(1), 15 (1990).
G. A. Rankin and F. E. Wright, Am. J. Sci. 39(1), 11 (1915).
K. R. Bonnickson, J. Phys. Chem. 59, 220 (1955).
A. S. Tolkacheva, S. N. Shkerin, S. V. Plaksin, et al., Zh. Prikl. Khim. 84, 880 (2012).
K. Hayashi, M. Hirano, and H. Hosono, J. Phys. Chem. B 109, 11900 (2005).
J. Jeevaratnam, L. S. D. Glasser, and F. P. Glasser, Nature 194(4830), 764 (1962).
M. Görnerup and O. Wijk, ISIJ Int., No. 12, 1465 (1996).
H. Bartl and T. Scheller, Neues Jahrb. Mineral. Monatsh. 35, 547 (1970).
S. N. Shkerin and A. S. Tolkacheva, Pat. Appl. No. 2010-125373, Russia.
A. V. Kuzmin, V. P. Gorelov, B. T. Melech, et al., Solid State Ionics 162–163, 13 (2003).
S. N. Shkerin, D. I. Bronin, S. A. Kovyazina, et al., Solid State Ionics 171, 129 (2004).
S. N. Shkerin, D. I. Bronin, S. A. Kovyazina, et al., Zh. Strukt. Khim. 44, 249 (2003).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Tolkacheva, S.N. Shkerin, I.V. Korzun, S.V. Plaksin, V.R. Khrustov, D.P. Ordinartsev, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 7, pp. 1089–1093.
Rights and permissions
About this article
Cite this article
Tolkacheva, A.S., Shkerin, S.N., Korzun, I.V. et al. Phase transition in mayenite Ca12Al14O33 . Russ. J. Inorg. Chem. 57, 1014–1018 (2012). https://doi.org/10.1134/S0036023612070182
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023612070182