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Coordination of 5,10,15,20-tetraphenyl-21H,23H-porphin by rhenium in various oxidation states

  • Physical Chemistry of Solutions
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Abstract

A method was developed for the synthesis of three rhenium complexes, (5,10,15,20-tetraphenyl-21H,23H-porphinato)(phenoxo)rhenium(III) (PhO)ReTPP, (5,10,15,20-tetraphenyl-21H,23H-porphi-nato)(chloro)rhenium(III) (Cl)ReTPP, and μ-oxo-bis[(oxo)-(5,10,15,20-tetraphenyl-21H,23H-porphi-nato)rhenium(V)] [O=ReTPP]2O, by one reaction between porphyrin H2TPP and H2ReCl6 in boiling phenol. In the complex formation reaction accompanied by the redox process, only the metal cation is involved in the transformation. Rhenium(IV) as chlororhenic acid dispropoportionates without participation of solvent or porphyrin to give Re(III) and Re(V) complexes. The chemical structures of the products were established by spectral and elemental analysis. Characteristics of the UV, Vis, IR, and 1H NMR spectra, the chromatographic mobility, and stability of the complexes were determined.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045, Russia

    E. Yu. Tyulyaeva, N. G. Bichan, T. N. Lomova & E. G. Mozhzhukhina

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  1. E. Yu. Tyulyaeva
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  2. N. G. Bichan
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  3. T. N. Lomova
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  4. E. G. Mozhzhukhina
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Original Russian Text © E.Yu. Tyulyaeva, N.G. Bichan, T.N. Lomova, E.G. Mozhzhukhina, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 9, pp. 1378–1384.

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Tyulyaeva, E.Y., Bichan, N.G., Lomova, T.N. et al. Coordination of 5,10,15,20-tetraphenyl-21H,23H-porphin by rhenium in various oxidation states. Russ. J. Inorg. Chem. 57, 1295–1301 (2012). https://doi.org/10.1134/S0036023612090203

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