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Synthesis and spectral properties of cobalt(II) and cobalt(III) tetraarylporphyrinates

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Abstract

Reactions of 5,10,15,20-tetraphenylporphin, 5,10,15,20-tetra(4′-methoxyphenyl)porphyrin, and 5,10,15,20-tetra(4′-chlorophenyl)porphyrin with cobalt(II) acetate in dimethylformamide were studied by spectrophotometry. The corresponding cobalt(II) porphyrinates were synthesized and identified. The corresponding cobalt porphyrinates in +3 oxidation state were obtained by reaction of cobalt(II) 5,10,15,20-tetraphenylporphyrinate and cobalt(II) 5,10,15,20-tetra(4′-methoxyphenyl)porphyrinate with 2,3-dichloro-5,6-dicyano-p-benzoquinone in chloroform. The oxidation of cobalt(II) 5,10,15,20-tetra(4′-chlorophenyl)porphyrinate with hydrochloric acid in dimethylformamide leads to cobalt(III) porphyrinate.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia

    N. V. Chizhova, R. S. Kumeev & N. Zh. Mamardashvili

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  1. N. V. Chizhova
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  2. R. S. Kumeev
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  3. N. Zh. Mamardashvili
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Original Russian Text © N.V. Chizhova, R.S. Kumeev, N.Zh. Mamardashvili, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 6, pp. 836–840.

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Chizhova, N.V., Kumeev, R.S. & Mamardashvili, N.Z. Synthesis and spectral properties of cobalt(II) and cobalt(III) tetraarylporphyrinates. Russ. J. Inorg. Chem. 58, 740–743 (2013). https://doi.org/10.1134/S0036023613060089

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  • DOI: https://doi.org/10.1134/S0036023613060089

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