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Synthesis, crystal structure, and electroluminescent properties of zinc and cadmium tetradentate azomethine complexes

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Abstract

Chemical and electrochemical syntheses of zinc(II) and cadmium(II) complexes based on tetradentate Schiff bases (H2L1 and H2L2) resulting from condensation of 2-tosylaminobenzaldehyde with 3,6-dioxa-1,8-octanediamine or 4,9-dioxa-1,12-dodecanediamine were performed. The structure, composition, and properties of the complexes were studied by elemental analysis, IR, 1H NMR, and UV spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction. The zinc(II) and cadmium(II) complexes luminesce in a DMF solution in the blue spectral region (λPL = 425–433 nm), the photoluminescence quantum yield φ being 0.25–0.30. Multilayer zinc(II)- and cadmium(II)-based electroluminescent structures with green-blue emission of the exciplex nature were fabricated.

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References

  1. C. W. Tang and S. A. VanSlyke, Appl. Phys. Lett. 51, 913 (1987).

    Article  CAS  Google Scholar 

  2. S. Wang, Coord. Chem. Rev. 215, 79 (2001).

    Article  CAS  Google Scholar 

  3. T. Sano, Y. Nishio, Y. Hamada, et al., J. Mater. Chem. 10, 157 (2000).

    Article  CAS  Google Scholar 

  4. I. K. Yakushchenko, M. G. Kaplunov, S. N. Shamaev, et al., RF Patent No. 2140956 (1999).

    Google Scholar 

  5. S. M. Kim, J. S. Kim, D. M. Shin, et al., Bull. Korean Chem. Soc. 22, 743 (2001).

    CAS  Google Scholar 

  6. D. Zhu, Z. Su, Z. Mu, et al., J. Coord. Chem. 59, 409 (2006).

    Article  CAS  Google Scholar 

  7. V. Amendola, Y. D. Fernandez, C. Mangano, et al., Dalton Trans., 4340 (2003).

    Google Scholar 

  8. G. Yu, Y. Liu, Y. Song, et al., Synth. Met. 117, 211 (2001).

    Article  CAS  Google Scholar 

  9. N. Chantarasiri, V. Ruangpornvisuti, N. Muangsin, et al., J. Mol. Struct. 701, 93 (2004).

    Article  CAS  Google Scholar 

  10. T. Yu, W. Su, W. Li, et al., Inorg. Chim. Acta 359, 2246 (2006).

    Article  CAS  Google Scholar 

  11. T. Yu, K. Zhang, Y. Zhao, et al., Inorg. Chim. Acta 361, 233 (2008).

    Article  CAS  Google Scholar 

  12. P. Wang, Z. Hong, Z. Xie, et al., Chem. Commun., 1664 (2003).

    Google Scholar 

  13. M. R. Bermejo, M. Vazquez, J. Sanmartin, et al., New J. Chem. 26, 1365 (2002).

    Article  CAS  Google Scholar 

  14. A. V. Metelitsa, A. S. Burlov, S. O. Bezuglyi, et al., RF Patent No. 2295527 (2007).

    Google Scholar 

  15. A. V. Metelitsa, A. S. Burlov, S. O. Bezuglyi, et al., Russ. J. Coord. Chem. 32, 858 (2006).

    Article  CAS  Google Scholar 

  16. N. I. Chernova, Yu. S. Ryabokobylko, V. G. Brudz’, and B. M. Bolotin, Zh. Org. Khim. 7, 1680 (1971).

    CAS  Google Scholar 

  17. A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A 603, 95 (2009).

    Article  CAS  Google Scholar 

  18. M. Newville, J. Synchrotron Rad., No. 8, 96 (2001).

    Google Scholar 

  19. S. I. Zabinski, J. J. Rehr, A. Ankudinov, and R. C. Alber, Phys. Rev. B 52, 2995 (1995).

    Article  Google Scholar 

  20. M. J. Frisch, G. W. Trucks, H. B. Schlegel, et al., Gaussian 03, Rev. A.1, Gaussian, Inc., Pittsburgh PA, 2003.

    Google Scholar 

  21. C. Lee, W. Yang, and R. G. Parr, Phys. Rev. 37, 785 (1988).

    Article  CAS  Google Scholar 

  22. A. D. Becke, J. Chem. Phys. 98, 5648 (1993).

    Article  CAS  Google Scholar 

  23. G. A. Petersson, A. Bennett, T. G. Tensfeldt, et al., J. Chem. Phys. 89, 2193 (1988).

    Article  CAS  Google Scholar 

  24. G. M. Sheldrick, Program for the Refinement of Crystal Structure. Göttingen, Germany (1997).

    Google Scholar 

Download references

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    A. S. Burlov, D. A. Garnovskii, N. V. Polosareva, A. S. Cheprasov, G. S. Borodkin & A. V. Metelitsa

  2. Research Institute of Physics, Southern Federal University, pr. Stachki 194, Rostov-on-Don, 344090, Russia

    V. G. Vlasenko

  3. Southern Scientific Center, Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344006, Russia

    D. A. Garnovskii

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    A. S. Antsyshkina, G. G. Sadikov, V. S. Sergienko & A. V. Churakov

  5. National Research Centre “Kurchatov Institute”, pl. Akademika Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

  6. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117071, Russia

    E. I. Mal’tsev, A. V. Dmitriev & D. A. Lypenko

Authors
  1. A. S. Burlov
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  2. V. G. Vlasenko
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  3. D. A. Garnovskii
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  4. N. V. Polosareva
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  5. A. S. Antsyshkina
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  6. G. G. Sadikov
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  7. V. S. Sergienko
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  8. A. V. Churakov
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  9. Ya. V. Zubavichus
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  10. E. I. Mal’tsev
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  11. A. V. Dmitriev
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  12. D. A. Lypenko
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  13. A. S. Cheprasov
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  14. G. S. Borodkin
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  15. A. V. Metelitsa
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Corresponding author

Correspondence to A. S. Burlov.

Additional information

Original Russian Text © A.S. Burlov, V.G. Vlasenko, D.A. Garnovskii, N.V. Polosareva, A.S. Antsyshkina, G.G. Sadikov, V.S. Sergienko, A.V. Churakov, Ya.V. Zubavichus, E.I. Mal’tsev, A.V. Dmitriev, D.A. Lypenko, A.S. Cheprasov, G.S. Borodkin, A.V. Metelitsa, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 7, pp. 934–946.

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Burlov, A.S., Vlasenko, V.G., Garnovskii, D.A. et al. Synthesis, crystal structure, and electroluminescent properties of zinc and cadmium tetradentate azomethine complexes. Russ. J. Inorg. Chem. 59, 721–732 (2014). https://doi.org/10.1134/S0036023614070031

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  • DOI: https://doi.org/10.1134/S0036023614070031

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