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EuNdCuS3: Crystal structure of the high-temperature polymorph and properties

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Abstract

The X-ray diffraction structure of the high-temperature polymorph of complex sulfide EuNdCuS3 is determined. The phase we prepared has an orthorhombic structure with the unit cell parameters a = 8.0648(3) Å, b = 4.0207(1) Å, c = 15.7924(3) Å, space group Pnma, Z = 4, Ba2MnS3 type structure. The sample is IR transparent in the range 1800–2800 cm−1. Thermal expansion coefficient is found to experience jumps, which are characteristic of phase transitions.

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Authors and Affiliations

  1. Tyumen State University, ul. Semakova 10, Tyumen, 625003, Russia

    A. V. Ruseikina, O. V. Andreev & A. A. Kislitsyn

  2. Institute of Chemistry and Chemical Engineering, Siberian Branch, Russian Academy of Sciences, ul. Karla Marksa 42, Krasnoyarsk, 660049, Russia

    L. A. Solovyev

Authors
  1. A. V. Ruseikina
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  2. L. A. Solovyev
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  3. O. V. Andreev
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  4. A. A. Kislitsyn
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Corresponding author

Correspondence to A. V. Ruseikina.

Additional information

Original Russian Text © A.V. Ruseikina, L.A. Solovyev, O.V. Andreev, A.A. Kislitsyn, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 10, pp. 1346–1351.

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Ruseikina, A.V., Solovyev, L.A., Andreev, O.V. et al. EuNdCuS3: Crystal structure of the high-temperature polymorph and properties. Russ. J. Inorg. Chem. 59, 1109–1114 (2014). https://doi.org/10.1134/S0036023614100143

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  • DOI: https://doi.org/10.1134/S0036023614100143

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