Abstract
An acoustic study of the binary Alamine 308 (triisooctylamine)-benzene system was performed by measuring ultrasonic velocity, viscosity and density. Interactions in the liquid mixture were explained on the basis of excess non-linearity parameters and other relevant data, such as the degree of molecular interaction, molar sound velocity, etc. In addition, the experimental velocities were compared with theoretical estimates using various empirical relations, and the relative merits of the corresponding theories and relations were discussed in terms of percentage variations. The basic aim of this work was to assess the type of solute-solvent interaction between a nonpolar extractant (Alamine 308) and a nonpolar diluent (benzene).
Similar content being viewed by others
References
Literature of Alamine 308 (Henkel Co., Ireland).
A. Aydin, Bull. Tech. Univ. Istanbul 36, 31 (1983).
T. Sato, T. Nukamura, and M. Kuwahara, Solv. Extr. Ion Exch. 3, 283 (1985).
D. A. White, Fathurrachman, Hydrometallurgy 36(2), 161 (1996).
S. Mishra, S. Mohanty, and V. Chakrovortty, Radiochim. Acta 69, 195 (1995).
K. C. Rout, P. K. Mishra, V. Chakravortty, and K. C. Dash, J. Radioanal. Nucl. Chem., Articles 181, 3 (1994).
A. N. Kannapan, R. Kesavaswamy, and A. Rajendran, J. Pure Appl. Ultrason. 15, 29 (1993).
T. S. Prasad and P. Venkateswarlu, J. Pure Appl. Ultrason. 17, 59 (1995).
S. Kamila, V. Chakravortty, and S. Jena, J. Solution. Chem. 33, 363 (2004).
S. Kamila, A. Mukherjee, V. Chakravortty, et al., J. Mol. Liq. 115, 127 (2004).
S. Kamila, S. Jena, and B. B. Swain, J. Chem. Thermodyn. 37, 820 (2005).
O. Nomoto, J. Phys. Soc. Jpn. 8, 553 (1953); 13, 1528 (1958).
W. van Dael and E. Vangeel, in Proceedings of the First International Conference on Calorimetry Thermodynamics (Warshaw, 1969), p. 555.
A. Ali, A. Yasmin, A. K. Nain, et al., Indian J. Pure Appl. Phys. 40, 315 (2002).
M. Rastogi, A. Awasthi, M. Gupta, et al., Indian J. Pure Appl. Phys. 40, 256 (2002).
C. V. Suryanarayana, Indian J. Chem. 10, 713 (1972).
M. R. Rao, J. Chem. Phys. 9, 682 (1941).
Y. Wada, J. Phys. Soc. Jpn. 45, 280 (1949).
A. Ali, A. K. Nain, and M. Kamil, Thermochim. Acta 274, 209 (1996).
O. Redlich and A. T. Kister, Ind. Eng. Chem. 40, 345 (1948).
N. Swain, S. K. Singh, D. Panda, and V. Chakravortty, J. Mol. Liq. 85, 321 (2000).
B. Jacobson, Acta Chem. Scand. 6, 1485 (1952).
S. Glasstone, Text Book of Physical Chemistry, 2nd ed. (Macmillan, 1995).
R. Vijayakumar, S. Vishwanathan, and A. Rao, J. Chem. Eng. Data 41b, 755 (1996).
J. D. Pandey, G. P. Dubey, B. P. Sukla, and S. N. Dubey, J. Pure Appl. Ultrason. 15, 33 (1993).
O. Prakash, A. Srivastava, A. Srivastava, and S. Prakash, Indian J. Pure Appl. Phys. 24, 306 (1986).
R. J. Fort and W. R. Moore, Trans. Faraday Soc. 61, 2102 (1965).
P. R. Palaniappan, A. N. Kannappan, and M. Kamalakannan, Z. Phys. Chem. 229, 779 (1988).
S. Baluja and S. Oja, Fluid Phase Equilib. 178, 233 (2001).
S. Baluja and S. Oja, Fluid Phase Equilib. 200, 11 (2002).
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Kamila, S., Kamilla, S.K., Singh, S.K. et al. A physicochemical study of binary mixtures of commercial solvent extractant, Alamine 308, with benzene at 303.15 K. Russ. J. Phys. Chem. 81, 1789–1793 (2007). https://doi.org/10.1134/S003602440711012X
Received:
Issue Date:
DOI: https://doi.org/10.1134/S003602440711012X