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Monodisperse microbeads of hypercrosslinked polystyrene for liquid and supercritical fluid chromatography

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Abstract

Monodisperse styrene–divinylbenzene (1 wt %) copolymer microbeads are obtained via the elaborate method of high-productivity precipitation polymerization. The crosslinking of this copolymer with chloromethyl methyl ether in the presence of Friedel–Crafts catalyst yields porous hypercrosslinked polymers with degrees of crosslinking that range from 200 to 500%. Microbead sorbents are shown to be suited for selective stationary phases for high-performance liquid chromatography and supercritical fluid chromatography.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Moscow, 119991, Russia

    M. P. Tsyurupa, Z. K. Blinnikova, M. M. Il’in & V. A. Davankov

  2. Kurnakov Institute of General and Inorganic Chemistry, Moscow, 117901, Russia

    O. O. Parenago, O. I. Pokrovskii & O. I. Usovich

Authors
  1. M. P. Tsyurupa
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  2. Z. K. Blinnikova
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  3. M. M. Il’in
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  4. V. A. Davankov
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  5. O. O. Parenago
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  6. O. I. Pokrovskii
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  7. O. I. Usovich
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Corresponding author

Correspondence to M. P. Tsyurupa.

Additional information

Original Russian Text © M.P. Tsyurupa, Z.K. Blinnikova, M.M. Il’in, V.A. Davankov, O.O. Parenago, O.I. Pokrovskii, O.I. Usovich, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 11, pp. 1802–1809.

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Tsyurupa, M.P., Blinnikova, Z.K., Il’in, M.M. et al. Monodisperse microbeads of hypercrosslinked polystyrene for liquid and supercritical fluid chromatography. Russ. J. Phys. Chem. 89, 2064–2071 (2015). https://doi.org/10.1134/S0036024415110217

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  • DOI: https://doi.org/10.1134/S0036024415110217

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