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Oxidative alkoxylation of phosphine in alcohol solutions of copper halides

  • Chemical Kinetics and Catalysis
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Abstract

The phosphine oxidation reaction with oxygen in alcohol solutions of copper (I, II) halides is studied. Kinetic parameters, intermediates, and by-products are studied by means of NMR 31Р-, IR-, UV-, and ESR- spectroscopy; and by magnetic susceptibility, redox potentiometry, gas chromatography, and elemental analysis. A reaction mechanism is proposed, and the optimum conditions are found for the reaction of oxidative alkoxylation phosphine.

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Authors and Affiliations

  1. Sokolskii Institute of Organic Catalysis and Electrochemistry, Almaty, 050010, Kazakhstan

    G. S. Polimbetova, A. K. Borangazieva, Zh. U. Ibraimova, G. O. Bugubaeva & S. Keynbay

Authors
  1. G. S. Polimbetova
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  2. A. K. Borangazieva
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  3. Zh. U. Ibraimova
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  4. G. O. Bugubaeva
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  5. S. Keynbay
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Corresponding author

Correspondence to G. S. Polimbetova.

Additional information

Original Russian Text © G.S. Polimbetova, A.K. Borangazieva, Zh.U. Ibraimova, G.O. Bugubaeva, S. Keynbay, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 8, pp. 1170–1175.

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Polimbetova, G.S., Borangazieva, A.K., Ibraimova, Z.U. et al. Oxidative alkoxylation of phosphine in alcohol solutions of copper halides. Russ. J. Phys. Chem. 90, 1539–1544 (2016). https://doi.org/10.1134/S0036024416080227

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  • DOI: https://doi.org/10.1134/S0036024416080227

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