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Application of silica-supported Fe–Cu nanoparticles in the selective hydrogenation of p-dinitrobenzene to p-phenylenediamine

  • Nanomaterials and Environment
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Abstract

Supported bimetallic Fe–Cu/SiO2 materials are synthesized, and their catalytic activity in hydrogenation of dinitrobenzene to phenylenediamine at 145–180°С and 1.3 MPa hydrogen pressure is studied for the first time. The best results (89% selectivity toward p-phenylenediamine at complete conversion of p-dinitrobenzene) are obtained for the sample synthesized via co-deposition with subsequent calcination at 300°С. The sample contains 7% iron and 3% copper. The formation of separate phases of metal oxides (for the catalysts prepared by impregnation) and mixed bimetallic oxide phases (in case of co-deposition procedure) in calcined samples is revealed via thermoprogrammed reduction with hydrogen.

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References

  1. A. I. Kozlov and V. L. Zbarskii, Ross. Khim. Zh., No. 3, 131 (2006).

    Google Scholar 

  2. S. Z. Levin, Processes of Catalytic Hydrogenation in Production of Monomers and Intermediates (Khimiya, Moscow, 1966), p. 128 [in Russian].

    Google Scholar 

  3. L. Zhao, J. Chen, and J. Zhang, J. Mol. Catal. A: Chem., 140 (2006).

  4. Y. Liu, J. Chen, J. Zhang, et al., Chem. Eng. Sci. 15, 63 (2007).

    CAS  Google Scholar 

  5. N. M. Yoon, Bull. Korean Chem. Soc. 14, 281 (1993).

    CAS  Google Scholar 

  6. M. M. Telkar, J. M. Nadgeri, C. V. Rode, et al., Appl. Catal. A: Gen. 295, 23 (2005).

    Article  CAS  Google Scholar 

  7. F. Cárdenas-Lizana, S. Gómez-Quero, C. J. Baddeley, et al., Appl. Catal. A: Gen. 387, 155 (2010).

    Article  Google Scholar 

  8. M. H. Brijaldo, F. B. Passos, H. A. Rojas, et al., Catal. Lett. 144, 860 (2014).

    Article  CAS  Google Scholar 

  9. A. A. Shesterkina, L. M. Kozlova, O. A. Kirichenko, et al., Russ. Chem. Bull. 65, 432 (2016).

    Article  CAS  Google Scholar 

  10. A. A. Shesterkina, O. A. Kirichenko, L. M. Kozlova, et al., Mendeleev Commun. 26, 228 (2016).

    Article  CAS  Google Scholar 

  11. L. M. Kustov, S. R. Al-Abed, O. A. Kirichenko, et al., Pure Appl. Chem. 86, 1141 (2014).

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Shesterkina, E. V. Shuvalova, O. A. Kirichenko, A. A. Strelkova, V. D. Nissenbaum, G. I. Kapustin & L. M. Kustov

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    L. M. Kustov

Authors
  1. A. A. Shesterkina
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  2. E. V. Shuvalova
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  3. O. A. Kirichenko
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  4. A. A. Strelkova
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  5. V. D. Nissenbaum
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  6. G. I. Kapustin
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  7. L. M. Kustov
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Corresponding author

Correspondence to A. A. Shesterkina.

Additional information

Original Russian Text © A.A. Shesterkina, E.V. Shuvalova, O.A. Kirichenko, A.A. Strelkova, V.D. Nissenbaum, G.I. Kapustin, L.M. Kustov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 2, pp. 201–204.

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Shesterkina, A.A., Shuvalova, E.V., Kirichenko, O.A. et al. Application of silica-supported Fe–Cu nanoparticles in the selective hydrogenation of p-dinitrobenzene to p-phenylenediamine. Russ. J. Phys. Chem. 91, 201–204 (2017). https://doi.org/10.1134/S0036024417020285

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  • DOI: https://doi.org/10.1134/S0036024417020285

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