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Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

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Abstract

The reaction of isobutylene hydroxycarbonylation with carbon monoxide and an alcohol (ethanol, 1-menthol) in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalytic system was investigated. It was shown that the reaction proceeds regioselectively with the formation of linear products (ethyl isovalerate, 1-menthyl isovalerate). The optimum conditions for running the process were found, at which the yield of the main products is 67–79%.

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Authors and Affiliations

  1. Al-Farabi Kazakh National University, ul. Al-Farabi 71, Almaty, 050038, Kazakhstan

    Kh. A. Suerbaev, G. Zh. Zhaksylykova, K. S. Kanybetov, T. K. Turkbenov & G. M. Abyzbekova

  2. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, 142432, Russia

    E. G. Chepaikin

Authors
  1. Kh. A. Suerbaev
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  2. E. G. Chepaikin
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  3. G. Zh. Zhaksylykova
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  4. K. S. Kanybetov
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  5. T. K. Turkbenov
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  6. G. M. Abyzbekova
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Corresponding author

Correspondence to E. G. Chepaikin.

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Original Russian Text © Kh.A. Suerbaev, E.G. Chepaikin, G.Zh. Zhaksylykova, K.S. Kanybetov, T.K. Turkbenov, G.M. Abyzbekova, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 3, pp. 208–211.

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Suerbaev, K.A., Chepaikin, E.G., Zhaksylykova, G.Z. et al. Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system. Pet. Chem. 48, 206–209 (2008). https://doi.org/10.1134/S0965544108030067

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  • DOI: https://doi.org/10.1134/S0965544108030067

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