Abstract
Decomposition of cumene hydroperoxide (CHP) in benzene, chlorobenzene, and carbon tetra-chloride in the presence of magnesium 2-ethylhexanoate has been investigated. It has been determined and kinetically proved that the degradation is preceded by the formation of an intermediate hydroperoxide-catalyst complex; the thermodynamic parameters of the complex formation have been determined. It has been found that the catalytic activity of magnesium 2-ethylhexanoate in carbon tetrachloride is higher than in chlorobenzene and benzene. The stability of the complex depending on the nature of the solvent decreases in the order C6H5Cl > CCl4 > C6H6.
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Original Russian Text © N.M. Nurullina, N.N. Batyrshin, Kh.E. Kharlampidi, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 1, pp. 66–69.
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Nurullina, N.M., Batyrshin, N.N. & Kharlampidi, K.E. Effect of the solvent nature on the magnesium 2-ethylhexanoate-catalyzed decomposition of cumene hydroperoxide. Pet. Chem. 54, 65–68 (2014). https://doi.org/10.1134/S0965544114010095
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DOI: https://doi.org/10.1134/S0965544114010095