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Direct catalytic oxidation of lower alkanes in ionic liquid media

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Abstract

Immobilization of rhodium (palladium)-copper-chloride catalytic systems in ionic liquids as high-boiling-point solvents affects the distribution of propane oxidation products: the acetone yield increases and the yield of alcohols decreases. Propane is oxidized to acetone, bypassing the isopropanol formation step. Methane is oxidized under more severe conditions than propane, giving methyl trifluoroacetate as the main product. Mechanisms of action of the catalytic systems based on rhodium and palladium are close to each other and likely include oxo or peroxo complexes as intermediates.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Russia

    E. G. Chepaikin, A. P. Bezruchko & G. N. Menchikova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    N. I. Moiseeva & A. E. Gekhman

Authors
  1. E. G. Chepaikin
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  2. A. P. Bezruchko
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  3. G. N. Menchikova
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  4. N. I. Moiseeva
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  5. A. E. Gekhman
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Corresponding author

Correspondence to E. G. Chepaikin.

Additional information

Original Russian Text © E.G. Chepaikin, A.P. Bezruchko, G.N. Menchikova, N.I. Moiseeva, A.E. Gekhman, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 5, pp. 380–387.

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Chepaikin, E.G., Bezruchko, A.P., Menchikova, G.N. et al. Direct catalytic oxidation of lower alkanes in ionic liquid media. Pet. Chem. 54, 374–381 (2014). https://doi.org/10.1134/S096554411405003X

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  • DOI: https://doi.org/10.1134/S096554411405003X

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