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Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

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Abstract

Guaiacol hydrogenation in an aqueous medium in the presence of a palladium catalyst supported on a mesoporous dendrimer-containing polymer and the effect of addition of sulfuric acid to the catalyst system have been studied. It has been found that the main hydrogenation product is 2-methoxycyclohexanol. After the addition of sulfuric acid to the catalyst system, the reaction mechanism significantly changes and cyclohexanol becomes the main hydrogenation product.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    E. A. Karakhanov, M. P. Boronoev, T. Yu. Filippova & A. L. Maksimov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. L. Maksimov

Authors
  1. E. A. Karakhanov
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  2. M. P. Boronoev
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  3. T. Yu. Filippova
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  4. A. L. Maksimov
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Corresponding author

Correspondence to M. P. Boronoev.

Additional information

Original Russian Text © E.A. Karakhanov, M.P. Boronoev, T.Yu. Filippova, A.L. Maksimov, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 3.

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Karakhanov, E.A., Boronoev, M.P., Filippova, T.Y. et al. Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer. Pet. Chem. 58, 407–411 (2018). https://doi.org/10.1134/S0965544118050080

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  • DOI: https://doi.org/10.1134/S0965544118050080

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