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Gemini surfactant-nonionic polymer mixed micellar systems

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Abstract

Tensiometry, dynamic light scattering, and optical spectrophotometry are employed to quantitatively characterize the aggregation behavior of a gemini (dicationic) surfactant in aqueous solutions in the presence of poly(ethylene glycol) with a molecular mass of 20000 Da or a Pluronic F127 block copolymer with a molecular mass of 12600 Da. It is shown that the formation of surfactant-polymer mixed aggregates decreases the positive surface potential of gemini surfactant micelles and is one of the main reasons for weakening of the micellar catalytic effect in hydrolysis of carboxylic acid esters.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Akad. Arbuzova 8, Kazan, 420088, Russia

    A. B. Mirgorodskaya, E. I. Yatskevich, L. Ya. Zakharova & A. I. Konovalov

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  1. A. B. Mirgorodskaya
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  2. E. I. Yatskevich
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  3. L. Ya. Zakharova
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  4. A. I. Konovalov
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Additional information

Original Russian Text © A.B. Mirgorodskaya, E.I. Yatskevich, L.Ya. Zakharova, A.I. Konovalov, 2012, published in Kolloidnyi Zhurnal, 2012, Vol. 74, No. 1, pp. 96–103.

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Mirgorodskaya, A.B., Yatskevich, E.I., Zakharova, L.Y. et al. Gemini surfactant-nonionic polymer mixed micellar systems. Colloid J 74, 91–98 (2012). https://doi.org/10.1134/S1061933X11060135

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  • DOI: https://doi.org/10.1134/S1061933X11060135

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