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Colloidal catalysts based on iron(III) oxides. 1. Decomposition of hydrogen peroxide

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Abstract

The catalytic activity of a colloidal catalyst based on iron(III) oxides in decomposition of H2O2 is studied. The catalyst is obtained by hydrolysis followed by peptization of FeCl3 · 6H2O salt in water in the presence of 1% ethanol. The structure, composition, and size of colloidal particles of the catalyst are studied by the methods of Mössbauer spectroscopy, X-ray fluorescence, X-ray diffraction, and transmission electron microscopy. The obtained catalyst is based on α-Fe2O3 crystals with an admixture of other crystalline structures of iron oxides and carbon-containing compounds. The activity of the catalyst with respect to H2O2 decomposition undergoes nonlinear and nonmonotonic variations and its particle size enlarges beginning from 1 to 3 nm with increasing initial concentration of FeCl3 · 6H2O. The catalyst obtained under optimal conditions exhibits high activity corresponding to the most efficient agents of H2O2 decomposition.

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Authors and Affiliations

  1. Institute of Oil and Gas Problems, Russian Academy of Sciences, ul. Gubkina 3, Moscow, 119333, Russia

    V. I. Lesin

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    L. M. Pisarenko & O. T. Kasaikina

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  1. V. I. Lesin
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  2. L. M. Pisarenko
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  3. O. T. Kasaikina
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Correspondence to V. I. Lesin.

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Original Russian Text © V.I. Lesin, L.M. Pisarenko, O.T. Kasaikina, 2012, published in Kolloidnyi Zhurnal, 2012, vol.74, No. 1, pp. 90–95.

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Lesin, V.I., Pisarenko, L.M. & Kasaikina, O.T. Colloidal catalysts based on iron(III) oxides. 1. Decomposition of hydrogen peroxide. Colloid J 74, 85–90 (2012). https://doi.org/10.1134/S1061933X12010103

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  • DOI: https://doi.org/10.1134/S1061933X12010103

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